An Improved Asymmetric Nitroolefination of α-Alkyl-γ- and δ-lactones with Modified Nitroenamines

DOI: 10.1016/0040-4039(94)02175-B

Source and publish data:

Tetrahedron Letters p. 99 - 102 (1995)

Update date:2022-08-17

Topics:

Authors:

Node, Manabu

Kurosaki, Ryuichi

Hosomi, Kouichi

Inoue, Takehisa

Nishide, Kiyoharu

et al. et al.

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Article abstract of DOI:10.1016/0040-4039(94)02175-B

New chiral nitroenamines 4a,b were found to be very effective for asymmetric nitroolefination of α-alkyl-γ- and δ-lactones.The enantiomeric excess of the product ran up to 99percent.A possible chelation model for the transition state of the asymmetric nit

Full text of DOI:10.1016/0040-4039(94)02175-B

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