Tetrahedron Asymmetry p. 333 - 336 (1992)
Update date:2022-08-11
Topics:
Bloch, Robert
Brillet, Cecile
Nucleophilic addition of Grignard reagents to the tricyclic lactols 4 or 5 provides with very high selectivity syn or anti 1,4-diols, so that, starting from the scalemic lactol 1a, three of the four possible diastereoisomeric 1,4-diols 7 or 9 can be obtained.This new example of remote asymmetric induction is illustrated by the synthesis of optically pure (2R,5R)-2,5-hexanediol and (3S,6R)-4-decen-3,6-diol.
View MoreContact:+86-13914766747
Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
WUXI HONOR SHINE CHEMICAL CO.,LTD
Contact:+86-510-83593312
Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Shandong united-rising pharmaceutical cooperation.,ltd.
Contact:008653187965009
Address:171No., Jing5 Road, Shizhong District, Jinan, China
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
Doi:10.1002/anie.200352738
(2004)Doi:10.3987/R-1987-09-2419
(1987)Doi:10.1021/op0340661
(2003)Doi:10.1021/ja01301a057
(1936)Doi:10.1039/c39880001618
(1988)Doi:10.1002/adsc.201000906
(2011)