Journal of Physical Chemistry p. 10486 - 10488 (1993)
Update date:2022-08-11
Topics:
Engel, Paul S.
Owens, Walter H.
Wang, Chengrong
1,2-di-n-butylhydrazine in hexane solution has been oxidized to azo-n-butane with oxygen and Pd/C catalyst and with red mercuric oxide.Both methods led to the same calculated heat of hydrogenation (ΔHH) of the azo group in hexane, -16.4 +/- 0.3 kcal/mol.This value is 10.6 kcal/mol less exothermic than the ΔHH of carbon-carbon double bonds.
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