Bulletin of the Chemical Society of Japan p. 1244 - 1247 (1993)
Update date:2022-08-11
Topics:
Yi, Sang Ho
Ohashi, Syunsuke
Sato, Hisaya
Nomori, Hiroyuki
Organosilicon polymers containing thiophene and anthraquinone units in the main chain were synthesized using palladium catalyst.These polymers were soluble and showed a small UV absorption change by the substituents on the silicon atom.Some of the polymers exhibit cation doping (n-doping) by the electrochemical reduction, and this doping process seemed to depend on the kinds of substituents on silicon atom.These polymers showed electrical conductivity of 3 * 10-5 S cm1- when doped with sodium naphthalenide.
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