17888-49-2

Usage

Chemical Properties

Clear colorless liquid with an amber tinge

InChI:InChI=1/C10H12S2Si/c1-13(2,9-5-3-7-11-9)10-6-4-8-12-10/h3-8H,1-2H3

Upstream product

• 188290-36-0 thiophene 
• 75-78-5 dimethylsilicon dichloride 
• 1849-29-2 1,1,1-trideuteromethanol 
• 124733-24-0 1,1,2,2-tetramethyl-1,2-di(thiophen-2-yl)disilane 
• 5713-61-1 thiophen-2-yl magnesium bromide 
• 811-98-3 d⁽⁴⁾-methanol 
• 3141-27-3 2,5-dibromothiophen 
• 1003-09-4 2-bromothiophene 
• 67-56-1 methanol 
• 96-43-5 2-thienyl chloride 

Downstream Products

• 1273574-14-3 4-[5-(dimethylthiophen-2-yl-silanyl)-thiophen-2-yl]-benzonitrile 

Relevant academic research and scientific papers

Syntheses and Electrical Properties of Organosilicon Polymers Containing Thiophene and Anthraquinone Units

Organosilicon polymers containing thiophene and anthraquinone units in the main chain were synthesized using palladium catalyst.These polymers were soluble and showed a small UV absorption change by the substituents on the silicon atom.Some of the polymers exhibit cation doping (n-doping) by the electrochemical reduction, and this doping process seemed to depend on the kinds of substituents on silicon atom.These polymers showed electrical conductivity of 3 * 10-5 S cm1- when doped with sodium naphthalenide.

Electrochemical synthesis of bis(2-thienyl) silanes, 2-thienylchlorosilanes, bis[5-(2-bromothienyl)]silanes, and 5-(2-bromothienyl) dimethylchlorosilane, precursors of poly[(silanylene) thiophene]s

Bis(2-thienyl)silanes and bis[5-(2-bromothienyl)]silanes were synthesized by electrochemical reduction of monohalothiophenes (Br,C1) and 2,5-dibromothiophene respectively in the presence of a dichlorosilane in THF or DME, using an undivided cell, a sacrif

METHOD FOR PRODUCING ARYLSILANE COMPOUND CONTAINING HALOSILANE COMPOUND AS RAW MATERIAL

PROBLEM TO BE SOLVED: To provide a method for producing an arylsilane compound with low production cost. SOLUTION: A method for producing an arylsilane compound includes a reaction step for the cross-coupling reaction of a halosilane compound represented by general formula (A-1), (A-2), or (A-3) and an arylboronic acid pinacol ester in the presence of a nickel catalyst, a Lewis acid catalyst, and an organic base (R independently represent an aromatic hydrocarbon group, a heteroaromatic ring group, or a C1-20 hydrocarbon group; X independently represent a halogeno group or a trifluoromethanesulfonyloxy group). SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT

Synthesis and characterization of di-, tri- and tetraboronic acids based on phenyl- and thienylsilane cores

The synthesis of a series of di- tri- and tetraboronic acids based on respective phenyl- and thienylsilane cores is described. The optimal protocols involved lithiation of respective arylsilane precursors using either deprotonative lithiation or halogen/lithium exchange with n-BuLi followed by treatment of resultant intermediates with B(Oi-Pr)3 and subsequent hydrolysis, which afforded final products in good yields. X-ray crystal structures of selected diboronic derivatives were determined showing that hydrogen-bonding interactions of B(OH)2 groups are the main factor governing the supramolecular assembly.

PREPARATION OF 2,5-DISILYLATED THIOPHENE DERIVATIVES AND THEIR CONVERSION TO 2,5-DIHALO DERIVATIVES

2,5-Disilylated thiophenes were prepared and readily oxidized with m-chloroperbenzoic acid (m-CPBA) to give the corresponding 1,1-dioxides.The thiophene dioxide was converted to 2,5-dihalogenothiophene dioxides with halogenating agents.

Photolysis of 1,1,2,2-tetramethyl-1,2-bis-(2'-thienyl)disilane

Photolysis of 1,1,2,2-tetramethyl-1,2-bis-(2'-thienyl)disilane (I) in methanol/benzene leads to dimethyl-bis-(2'-thienyl)silane (III), 2-methoxydimethylsilylthiophene (IV) and 2-dimethylsilylthiophene (V) as a major products.The mechanism of this reaction, has been explored by use of methanol-d4.The predominant pathway leading to IV and V appears to involve direct reaction of methanol with the photoexcited state of I.