Journal of Organometallic Chemistry p. 9 - 16 (1984)
Update date:2022-08-11
Topics:
Gurskii, M. E.
Baranin, S. V.
Mikhailov, B. M.
3-Methoxy-7-methyl-3-borabicyclo<3.3.1>nonane (I) and 3-methoxy-7-methoxymethyl-3-borabicyclo<3.3.1>non-6-ene (X) react with α-halomethyllithium compounds at <= -110 deg C to yield 3-methoxy-8-methyl-3-borabicyclo<4.3.1>decane and a mixture of 3-methoxy-8-methoxymethyl-3-borabicyclo<4.3.1>dec-7-ene and 3-methoxy-8-methoxymethyl-3-borabicyclo<4.3.1>dec-8-ene.A similar reaction of I or X with α-bromomethyllithium leads to the corresponding endo-4- and exo-4-methyl derivatives of 3-borabicyclo<4.3.1>decane and 3-borabicyclo<4.3.1>dec-7(8)-ene.
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