Competitive Catalysis and Quenching by Amines of Photo-Smiles Rearrangement as Evidence for a Zwitterionic Triplet as the Proton-Donating Intermediate

DOI: 10.1021/ja00185a034

Source and publish data:

Journal of the American Chemical Society p. 1018 - 1022 (1989)

Update date:2022-08-31

Topics:

Authors:

Wubbels, Gene G.

Sevetson, Bradley R.

Sanders, Houston

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00185a034

Ten amine bases are observed to catalyze the photo-Smiles rearrangement of 4-O2NC6H4OCH2CH2NHPh in acetonitrile.Plots of (quantum yield)^-1 vs ^-1 are linear for all ten bases, but the intercepts representing limiting quantum yi

Full text of DOI:10.1021/ja00185a034

Products guided by the article

Product name:Ethanol, 2-[(4-nitrophenyl)phenylamino]-

Cas No:18226-18-1

R&D Labs maybe for 18226-18-1

Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road

Relevant to this article

Cross-coupling reactions of gold(I) alkynyl and polyyndiyl complexes

Doi:10.1016/j.jorganchem.2010.11.026
(2011)
Doi:10.1021/ja00419a029
(1976)
N-Benzoylbenzamidinate Complexes of Magnesium: Catalysts for the Ring-Opening Polymerization of ?-Caprolactone and CO₂/Epoxide Coupling

Doi:10.1021/acs.organomet.7b00617
(2017)
Mechanistic Investigations with the Aid of Isotopic Labeling, IX. Mechanism of the Ring Contraction Reaction of 1,4-Benzthiazin-2,3-4H-dione

Doi:10.1007/BF00799171
(1984)
Pseudosaccharin amines as potent and selective K_V1.5 blockers

Doi:10.1016/j.bmcl.2015.02.066
(2015)
Doi:10.1021/ja01110a053
(1953)

Article Doi