Preparation of (Trimethylsilyl)methyl Halides and Trifluoromethanesulfonate by Methylene Insertion Using Diazomethane

DOI: 10.1055/s-1988-27554

Source and publish data:

Synthesis p. 318 - 319 (1988)

Update date:2022-08-25

Topics:

Authors:

Lee, Jong Gun

Ha, Dong Soo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1988-27554

(Trimethylsilyl)methyl halides (1,3) and trifluoromethanesulfonate (triflate) (2) were prepared by inserting a methylene group into the silicon-heteroatom bond of trimethylsilyl halides and triflate using diazomethane.

Full text of DOI:10.1055/s-1988-27554

Products guided by the article

Product name:(BROMOMETHYL)TRIMETHYLSILANE

Cas No:18243-41-9

R&D Labs maybe for 18243-41-9

Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China

Relevant to this article

Doi:10.1021/ja02216a007
(1911)
Doi:10.1021/ja00728a065
(1970)
Synthesis, crystal structure and photophysical study of luminescent three-coordinate cuprous bromide complexes based on pyrazole derivatives

Doi:10.1080/00958972.2016.1139102
(2016)
Structural, photoluminescence, physical, optical limiting, and hirshfeld surface analysis of polymorphic chlorophenyl organic chalcone derivative for optoelectronic applications

Doi:10.1016/j.molstruc.2021.130053
(2021)
Doi:10.1021/ja01525a043
(1959)
Isolation and Characterization of Well-Defined Silica-Supported Azametallacyclopentane: A Key Intermediate in Catalytic Hydroaminoalkylation Reactions

Doi:10.1002/adsc.201500484
(2015)

Article Doi