18243-41-9 Usage
General Description
(BROMOMETHYL)TRIMETHYLSILANE is a chemical compound with the molecular formula C4H11BrSi. It is a clear, colorless liquid that is used as a reagent in organic synthesis. (BROMOMETHYL)TRIMETHYLSILANE contains a bromomethyl group attached to a trimethylsilyl group, making it a useful reagent for the introduction of both bromomethyl and trimethylsilyl groups into organic molecules. (BROMOMETHYL)TRIMETHYLSILANE is often used in the production of pharmaceuticals and in the modification of polymers, as well as in the synthesis of other organosilicon compounds. It is important to handle (BROMOMETHYL)TRIMETHYLSILANE with care, as it is highly reactive and can be toxic if not used properly.
Check Digit Verification of cas no
The CAS Registry Mumber 18243-41-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,2,4 and 3 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 18243-41:
(7*1)+(6*8)+(5*2)+(4*4)+(3*3)+(2*4)+(1*1)=99
99 % 10 = 9
So 18243-41-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H11BrSi/c1-6(2,3)4-5/h4H2,1-3H3
18243-41-9Relevant articles and documents
Radical Silyldifluoromethylation of Electron-Deficient Alkenes
Supranovich, Vyacheslav I.,Levin, Vitalij V.,Struchkova, Marina I.,Korlyukov, Alexander A.,Dilman, Alexander D.
, p. 3215 - 3218 (2017)
A reaction of bromo- and iododifluoromethyl-substituted silanes with electron-deficient alkenes in the presence of an N-heterocyclic carbene borane complex is described. The reaction is performed under irradiation with light-emitting diodes and proceeds v
Preparation of Trimethylsilylmethyl Derivatives Using Phase Transfer Methods
Ambasht, Saket,Chiu, Sai Keung,Peterson, Paul E.,Queen, Jeffrey
, p. 318 - 320 (1980)
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Electrophilic cleavages in (CH3)3SnCH2M(CH3)3 (M = Sn, Ge, Si, C). 1. Product distribution
Hawker, Darryl W.,Wells, Peter R.
, p. 821 - 825 (2008/10/08)
The extent to which Sn-CH2 and/or Sn-CH3 cleavage occurs in (CH3)3SnCH2M(CH3)3 (M = Sn, Ge, Si) in reactions with several electrophiles has been determined. With iodine and with
