Barbier-type reactions of aryl halides with ketones mediated by Samarium diiodide

DOI: 10.1248/cpb.42.2190

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2190 - 2192 (1994)

Update date:2022-08-28

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Authors:

Kunishima

Hioki Hioki

Kono Kono

Sakuma Sakuma

Tani Tani

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Article abstract of DOI:10.1248/cpb.42.2190

Barbier-type reaction of aryl halides with ketones took place on treatment with samarium diiodide in benzene containing 10% hexamethylphosphoric triamide (HMPA). The reaction involves an aryl samarium as an intermediate.

Full text of DOI:10.1248/cpb.42.2190

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