Journal of Organic Chemistry p. 7228 - 7237 (1993)
Update date:2022-08-16
Topics:
Snider, Barry B.
Vo, Nha Huu
Foxman, Bruce M.
Alylic cyclobutanols 1, 10, 21, 27, 32, 39, 51 and 58 are oxidatively fragmented by Mn(OAc)3*2H2O in EtOH to give tertiary radicals as shown in eq 1.These tertiary radicals undergo both 6-endo-cyclization to the α,β-unsaturated ketone to afford α-keto rad
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