Journal of the Chemical Society - Faraday Transactions p. 591 - 596 (1994)
Update date:2022-08-24
Topics:
Nagaishi, Ryuji
Jiang, Pei-Yun
Katsumura, Yosuke
Ishigure, Kenkichi
The primary yields of water radiolysis have been evaluated as a function of nitric acid or nitrate concentration in the 60Co γ-radiolysis of nitric acid and 0.4 mol dm-3 sulfuric acid with nitric acid or sodium nitrate solutions containing Ce(IV) and Ce(III), in the presence and absence of Tl(1+).The radiolytic decomposition of water is significantly enhanced in these systems, from gw(-H2O)=0.60 μmol J-1 for 0.4 mol dm-3 sulfuric acid-sodium nitrate solutions to gw(-H2O)=0.76 μmol J-1 for nitric acid solutions at high solute concentrations.
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