Journal of Chemical Thermodynamics p. 615 - 624 (1989)
Update date:2022-08-29
Topics:
Tan, Zhi-Cheng
Kamaguchi, Akeji
Nagano, Yatsuhisa
Sakiyama, Minoru
The standard enthalpy of formation of 2-chloro-6-(trichloromethyl)pyridine(cr) was determined to be -(55.4 +/- 1.8) kJ * mol-1 at 298.15 K by rotating-bomb oxygen combustion calorimetry using paraffin oil as a combustion aid and As2O3(aq) as a reducing agent for Cl2 formed.Nitric acid and chlorometallic acids of noble metals present in the final bomb solution were analysed by ion-chromatographic and atomic-absorption spectrometric methods, respectively.The effect of catalytic pre-oxidation of As2O3(aq) was evaluated.The standard molar energy of combustion was calculated using a computation form derived by combining that for CHON compounds with that for CHOCl compounds.The modifications of the form are described.
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