Chemistry Letters p. 1327 - 1328 (1991)
Update date:2022-08-11
Topics:
Kosugi, Masanori
Kurata, Hiroshi
Kawata, Ken-ichi
Migita, Toshihiko
Reaction of allyltris(trimethylsilyl)silane with organic halides under the free radical conditions resulted in allylation of the halides in moderate to good yields.The presence of three trimethylsilyl groups on the silicon could enhance the homolytic dissociation of a Si-C bond in the β-silylalkyl radical.
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