Allyltris(trimethylsilyl)silane as Radical Allylating Agent for Organic Halides

DOI: 10.1246/cl.1991.1327

Source and publish data:

Chemistry Letters p. 1327 - 1328 (1991)

Update date:2022-08-11

Topics:

Authors:

Kosugi, Masanori

Kurata, Hiroshi

Kawata, Ken-ichi

Migita, Toshihiko

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Article abstract of DOI:10.1246/cl.1991.1327

Reaction of allyltris(trimethylsilyl)silane with organic halides under the free radical conditions resulted in allylation of the halides in moderate to good yields.The presence of three trimethylsilyl groups on the silicon could enhance the homolytic dissociation of a Si-C bond in the β-silylalkyl radical.

Full text of DOI:10.1246/cl.1991.1327

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