
Helvetica Chimica Acta p. 430 - 437 (1986)
Update date:2022-08-17
Topics:
Vauthey, Eric
Suppan, Paul
Haselbach, Edwin
Davidson, Robert Stephen
Laser-flash-photolysis experiments show that, in MeCN at 20 deg, perylene (P) undergoes three distinct electron-transfer reactions: a) 1P* + MeCN -> P.+ + MeCN.- b) 1P* + P -> P.+ + P.- c) 3P* + 3P* -> (P x P)* -> P.+ + P.-.These processes originate probably from the thermally relaxed excited states of P.
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