Photoinduced Electron-Transfer Reactions of Perylene in Acetonitrile

DOI: 10.1002/hlca.19860690224

Source and publish data:

Helvetica Chimica Acta p. 430 - 437 (1986)

Update date:2022-08-17

Topics:

Authors:

Vauthey, Eric

Suppan, Paul

Haselbach, Edwin

Davidson, Robert Stephen

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Article abstract of DOI:10.1002/hlca.19860690224

Laser-flash-photolysis experiments show that, in MeCN at 20 deg, perylene (P) undergoes three distinct electron-transfer reactions: a) ¹P* + MeCN -> P^.+ + MeCN^.- b) ¹P* + P -> P^.+ + P^.- c) ³P* + ³P* -> (P x P)* -> P^.+ + P^.-.These processes originate probably from the thermally relaxed excited states of P.

Full text of DOI:10.1002/hlca.19860690224

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