Journal of Physical Chemistry p. 563 - 565 (1985)
Update date:2022-08-11
Topics:
Flowers, M. C.
Rabinovitch, B. S.
Chemically activated 3-ethyl-2-methyl-2-pentyl radicals were produced at 300 K by H-atom addition to 3-ethyl-2-methyl-2-pentene at hydrogen gas pressures of 15 to 10800 torr.These radicals can decompose to 2-methyl-2-pentene and an ethyl radical.The initially produced radical has a nonrandom energy distribution.Our observations help to clarify the size of the initially excited subset of vibrational modes; remaining uncertainty concerns the total number of internal rotational degrees of freedom to be included.An analogy exists to single photon vibrational excitation studies.
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