Journal of the American Chemical Society p. 845 - 850 (1984)
Update date:2022-08-11
Topics:
Andrist
DePuy
Squires
The isomeric 1-phenylcyclopropyl and 2-phenylallyl anions have been prepared in the gas phase by proton-abstraction reactions. They have been shown to be distinct, noninterconverting species by their differing reactions with D//2O, O//2, and N//2O. The 2-methyl-1-phenylcyclopropyl and 1-methyl-2-phenylallyl anions are also shown to react differently with these reagents. However, in the presence of H//2O the 1-methyl-2-phenylallyl anion is converted to the 1-methyl-1-phenylallyl anion by proton addition and reabstraction. The utility of these and other reagents for determining ion structure in the gas phase is discussed.
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