2-Functionalized allyl tris(trimethylsilyl)silanes as radical-based allylating agents

DOI: 10.1016/0040-4039(96)01354-8

Source and publish data:

Tetrahedron Letters p. 6387 - 6390 (1996)

Update date:2022-08-11

Topics:

Authors:

Chatgilialoglu, Chryssostomos

Ferreri, Carla

Ballestri, Marco

Curran, Dennis P.

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Article abstract of DOI:10.1016/0040-4039(96)01354-8

Radical allylations with 2-functionalized allyl tris(trimethylsilyl)silanes occur under mild conditions in good to excellent yield provided that the radical precursor and the silane have the appropriate electronic pairing. These reactions offer tin-free alternatives for transformations that are currently conducted with allyl stannenes.

Full text of DOI:10.1016/0040-4039(96)01354-8

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