Russian Chemical Bulletin p. 294 - 299 (1999)
Update date:2022-08-16
Topics:
Grinberg, V. A.
Koch, T. A.
Mazin, V. M.
Mysov, E. I.
Sterlin, S. R.
The possibility or anodic generation of a solvated proton on gas-diffusion electrode in an aprotic medium in the presence of carbon dioxide and 1,3-butadiene has been demonstrated. Formic acid was shown to be the only product of the reaction in the initially approtic medium with the use of a hydrogen gas-diffusion anode. The influence of the counterion on the reactivity of the CO2*- radical anion in electrocarboxylation was shown experimentally.
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