Regio- and stereospecificity in radical cascade cyclizations of TMS- alcyne containing allyl bromomethyldimethylsilyl ethers

DOI: 10.1016/S0040-4039(98)01107-1

Source and publish data:

Tetrahedron Letters p. 5367 - 5368 (1998)

Update date:2022-08-16

Topics:

Authors:

Belval, Florence

Chavis, Claude

Fruchier, Alain

Montero, Jean-Louis

Lucas, Marc

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Article abstract of DOI:10.1016/S0040-4039(98)01107-1

Tandem radical cyclization of (E) and (Z) TMS-homopropargyl allyl bromomethyldimehylsilyl ethers is reported to provide an all-cis substituted vinylcyclopentanol 5. Regio- and stereospecificity are discussed.

Full text of DOI:10.1016/S0040-4039(98)01107-1

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