A crossed molecular beams investigation of the reactions O(3P)+C6H6, C6D6

Article abstract of DOI:10.1063/1.439714

A crossed beams investigation of the reactions of O(³P)+C6H6, C6D6 has been carried out using a seeded, supersonic, atomic oxygen nozzle beam source.Angular and velocity distributions of reaction products have been used to identify the major reaction pathways.The initially formed triplet biradical, C6H6O (C6D6O), either decays by hydrogen (deuterium) elimination or becomes stabilized, most likely by nonradiative transition to the S₀ manifold of ground state phenol.CO elimination was not found to be a major channel.The branching ratio between H(D) atom elimination and stabilization was found to be sensitive to both collision energy and isotopic substitution.

Full text of DOI:10.1063/1.439714

A crossed molecular beams investigation of the reactions O(3 P)+ C6H6, C6D6
Steven J. Sibener, Richard J. Buss, Piergiorgio Casavecchia, Tomohiko Hirooka, and Yuan T. Lee
Citation: The Journal of Chemical Physics 72, 4341 (1980); doi: 10.1063/1.439714
View online: http://dx.doi.org/10.1063/1.439714
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/72/8?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.49.251.30 On: Tue, 02 Dec 2014 20:21:27