Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1567 - 1571 (1992)
Update date:2022-08-29
Topics:
Terent'ev, A. B.
Gapusenko, S. I.
Vasil'eva, T. T.
Vitt, S. V.
The relative rate constants of the addition of the C6H5CH2 radical to unsaturated compounds CH2=CHX (X = C4H9, SiMe3, CF3, CO2Me, CN) were determined under the conditions of initiation by the Fe(CO)5 + DMF system or by benzoyl peroxide.Depending on the values of the relative addition rate constants, the monomers can be arranged into the following series (X): CF3 ca.C4H9 < SiMe3
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