Tetrahedron Letters p. 2869 - 2872 (1983)
Update date:2022-08-17
Topics:
Shirahama, Haruhisa
Arora, Grudial S.
Osawa, Eiji
Matsumoto, Takeshi
Geometries and populations for four possible conformers of (Z,E,E)-humulene (1) were obtained by molecular mechanics calculations.Treatment of 1 with mercury salt gave 3,7-epoxy-3,6-secoprotoilludane (3) and 9,10-epoxide of 1 afforded tetramethylbicyclo<7.2.0>undecadienols (10, 11) on treatment with TMSOf.
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(1977)
