A highly stable porphyrinic zirconium metal-organic framework with shp-a topology

Article abstract of DOI:10.1021/ja510525s

Through a kinetically controlled synthetic process, we synthesized PCN-223, a new porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected Zr₆ cluster through an unusual disordered arrangement, giving rise to the first example of the shp-a network in MOFs. With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223(Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels-Alder reaction.

Full text of DOI:10.1021/ja510525s

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Communication
A Highly Stable Porphyrinic Zirconium Metal-
Organic Frame-work with shp-a Topology
Dawei Feng, Zhi-Yuan Gu, Ying-Pin Chen, Jihye Park, Zhangwen
Wei, Yujia Sun, Mathieu Bosch, Shuai Yuan, and Hong-Cai Zhou
J. Am. Chem. Soc., Just Accepted Manuscript • DOI: 10.1021/ja510525s • Publication Date (Web): 05 Dec 2014
Downloaded from http://pubs.acs.org on December 8, 2014
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†
zhou@mail.chem.tamu.edu
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