Acetylation and formylation of alcohols with triphenylphosphine and carbon tetrabromide in ethyl acetate or ethyl formate

DOI: 10.1016/S0040-4020(98)00255-5

Source and publish data:

Tetrahedron p. 5845 - 5852 (1998)

Update date:2022-08-31

Topics:

Authors:

Hagiwara, Hisahiro

Morohashi, Kimie

Sakai, Hitoshi

Suzuki, Toshio

Ando, Masayoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(98)00255-5

Alcohols were acetylated or formylated with triphenylphosphine and carbon tetrabromide in ethyl acetate or ethyl (or methyl) formate at room temperature. THP or TBDMS ether of primary alcohol got converted into formate or acetate under the experimental conditions employed in one pot operation.

Full text of DOI:10.1016/S0040-4020(98)00255-5

Products guided by the article

Product name:(9E)-octadec-9-en-1-yl acetate

Cas No:22147-38-2

R&D Labs maybe for 22147-38-2

Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Guangzhou Puho Pharmaceutical Technology Co. Ltd.

Contact:86-20-29848035/29848075

Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
WUHAN RISON TRADING CO.,LTD

Contact:0086-27-83607103/83642615

Address:No.498, Jianshe Ave, Wuhan, China

Relevant to this article

Synthesis and photopolymerization of novel, highly reactive phosphonated-urea-methacrylates for dental materials

Doi:10.1016/j.reactfunctpolym.2013.07.006
(2013)
Synthesis of chiral monoaza-15-crown-5 ethers from L-valinol and the enantiomeric recognition of chiral amines and their perchlorates salts

Doi:10.1016/j.tetasy.2003.09.037
(2003)
Substituent effects on the regioselectivity in fluorination of allylic alcohols with DAST

Doi:10.1016/S0022-1139(98)00115-8
(1998)
Synthesis and cytotoxic activity of benzopyranoxanthone analogues of benzo[b]acronycine and psorospermine

Doi:10.1248/cpb.49.675
(2001)
Total Synthesis of Maoecrystal P: Application of a Strained Bicyclic Synthon

Doi:10.1002/anie.201711084
(2018)
Doi:10.1021/ja00530a007
(1980)

Article Doi