Substituent effects on the regioselectivity in fluorination of allylic alcohols with DAST

DOI: 10.1016/S0022-1139(98)00115-8

Source and publish data:

Journal of Fluorine Chemistry p. 23 - 27 (1998)

Update date:2022-08-31

Topics:

Authors:

Boukerb, Abdelghani

Gree, Danielle

Laabassi, Mohammed

Gree, Rene

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Article abstract of DOI:10.1016/S0022-1139(98)00115-8

The regioselectivity of the fluorination of various allylic and β-dienoic alcohols with DAST has been studied. Substituent effects are important in these reactions; a strong preference for the secondary fluorides versus the primary ones is observed, especially in the case of alkyl and aryl substituted derivatives.

Full text of DOI:10.1016/S0022-1139(98)00115-8

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