Journal of Fluorine Chemistry p. 127 - 132 (1996)
Update date:2022-08-17
Topics:
Apsey, Glenn C.
Chambers, Richard D.
Odello, Paolo
Reactions involving perfluoro-2-iodopropane and 1,1-difluoroethene, give telomers (1) and these telomer iodides are coupled to give [(CF3)2CF(CH2CF2)n-]2 (2). Fluorodeiodination gives a series of compounds (CF3)2CF(CH2CF2)nF (3). Lewis acid-induced eliminations from these systems is very effective using SbF5 and cyclisations can also be induced by this methodology. A series of conjugated polymers is obtained by exposure of films of PVC, PVDF, and polytrifluoroethene to SbF5 vapour.
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