Catalytic transformations of oligocarbosilanes induced by AlCl3

DOI: 10.1007/BF02495273

Source and publish data:

Russian Chemical Bulletin p. 2147 - 2148 (1997)

Update date:2022-08-31

Topics:

Authors:

Chernyavskaya

Aleksinskaya

Zavin Zavin

Belokon'

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Article abstract of DOI:10.1007/BF02495273

Catalytic activation of Si - C bonds in poly(vinyltrimethylsilane) was studied using a model reaction of catalytic transformations of oligocarbosilanes Me₃Si(CH₂)_nSiMe₃ (n = 2, 3) in dichlorodimethylsilane in the presence of AlCl₃ as an example. The formation of ClMe₂Si(CH₂)_nSiMe₃ was established by chromato-mass spectrometry and GLC.

Full text of DOI:10.1007/BF02495273

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