Journal of Organic Chemistry p. 4918 - 4920 (1985)
Update date:2022-08-17
Topics:
Faghih, Ramine
Fontaine, Catherine
Horibe, Isao
Immamura, Paulo M.
Lukacs, Gabor
et al.
Tetra-O-acetylglucosidation-induced 1H nuclear magnetic resonance shifts were found highly characteristic of the absolute configuration of representative examples of R and S chiral secondary alcohols.The most important chemical shift changes of structurally diagnostic value for the determination of the absolute configuration of alcohols concern the protons of the aglycone attached to the carbons at β-position relative to the oxygen atom.
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Doi:10.1002/jlac.19687160114
(1968)Doi:10.3390/molecules24091793
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(2016)Doi:10.1002/anie.201606323
(2016)Doi:10.1039/c7dt02470c
(2017)Doi:10.1021/ja01172a031
(1949)