On The Mechanism of Asymmetric Dihydroxylation(AD) of Alkenes

DOI: 10.1016/S0040-4039(00)73153-4

Source and publish data:

Tetrahedron Letters p. 4209 - 4210 (1994)

Update date:2022-08-12

Topics:

Authors:

Lohray, Braj B.

Bhushan, Vidya

Nandanan, E.

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Article abstract of DOI:10.1016/S0040-4039(00)73153-4

1H NMR studies on bis(9-O-dihydroquinidinyl)terephthalate (DHQD2-TP) with various concentration of osmium tetroxide and trans-3-hexene reveal that OsO4 is bound to both the quinuclidine moieties of DHQD2-TP but only one of the bound OsO4 reacts with alkenes in the AD process.

Full text of DOI:10.1016/S0040-4039(00)73153-4

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