Titanocene(II)-promoted desulfurizative tertiary alkylation of 1,3- bis(phenylthio)alk-1-enes and β,γ-unsaturated thioacetals

DOI: 10.1016/S0040-4039(99)00975-2

Source and publish data:

Tetrahedron Letters p. 5353 - 5356 (1999)

Update date:2022-08-03

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Authors:

Takeda, Takeshi

Nozaki, Naoki

Saeki, Naoko

Fujiwara, Tooru

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Article abstract of DOI:10.1016/S0040-4039(99)00975-2

The desulfurization of 1,3-bis(phenylthio)alk-1-enes with the low valent titanium species Cp₂Ti[P(OEt)₃]₂ and subsequent reaction with tert-alkyl chlorides gave the terminal olefins regioselectively. The similar reactions

Full text of DOI:10.1016/S0040-4039(99)00975-2

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