Cobalt carbene ion: Reactions of Co+ with C2H4, cyclo-C3H6, and cyclo-C2H4O

Article abstract of DOI:10.1063/1.441453

An ion beam apparatus is employed to study the formation of the cobalt carbene ion, CoCH2⁺.This ion is produced in the endothermic reaction of cobalt ions with ethene and cyclopropane and in an exothermic reaction with ethylene oxide.A model is proposed to account for the dependence of experimental cross sections on relative kinetic energy for the endothermic reactions.Using this model to interpret the experimental results, a bond dissociation energy D deg(Co⁺-CH2) = 3.7 +/- 0.3 eV is derived.

Full text of DOI:10.1063/1.441453

Cobalt carbene ion: Reactions of Co+ with C2H4, cycloC3H6, and cycloC2H4O
P. B. Armentrout and J. L. Beauchamp
Citation: The Journal of Chemical Physics 74, 2819 (1981); doi: 10.1063/1.441453
View online: http://dx.doi.org/10.1063/1.441453
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/74/5?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.118.88.48 On: Tue, 12 Aug 2014 08:53:58