Journal of Physical Chemistry p. 1818 - 1821 (1983)
Update date:2022-08-11
Topics:
Slagle, Irene R.
Gutman, David
The chemical branching of three fluorine-atom reactions, those with C2H4, C2H3Cl, and C2H3Br, was studied in real-time experiments using a tubular reactor coupled to a photoionization mass spectrometer.The fluorine atoms were generated by the CO2-laser-induced secondary photolysis of C6F5Cl which also appears to produce tetrafluorobenzene (c-C6F4).The measured fractional extents that the three reactions studied proceed by a displacement route at 295 K (to yield C2H3F + X) are 0.65 (+/-0.06), 0.72 (+/-0.14), and 0.72(+/-0.14) for C2H4, C2H3Cl, and C2H3Br, respectively.
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