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Fig. 10. Perspective view of the network in 3 with the 2D-{Cd(l-SCN)2}-subnet
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unit is a zigzag chain. The molecular complexes and the 1D chain
structure feature hydrogen bonds for the 3D supramolecular pack-
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[ZnBr2(
l
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j
Npy,Ntz-pytz)] (2) are connected through C–HꢀꢀꢀBr and
C–HꢀꢀꢀNtriazole hydrogen bonds to a supramolecular 3D network.
The formation of 21 helices from the hydrogen and covalent bonds
with the same handedness or sense of rotation in a single crystal
leads to a homochiral network, which crystallized enantiomeri-
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pates in the 3D network with a 2D-{Cd(
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l
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Acknowledgment
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The work was supported by DFG Grant No. Ja466/14-1.
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Appendix A. Supplementary material
CCDC 814659, 814660 and 814661 contain the supplementary
crystallographic data for this paper. These data can be obtained
free of charge from The Cambridge Crystallographic Data Centre
associated with this article can be found, in the online version, at
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