Synthesis of fused aromatic [1,3]dioxoles from 2-hydroxymethylphenols

DOI: 10.1055/s-1997-1037

Source and publish data:

Synlett p. 1395 - 1396 (1997)

Update date:2022-08-29

Topics:

Authors:

Gesson, Jean-Pierre

Mondon, Martine

Pokrovska, Natacha

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Article abstract of DOI:10.1055/s-1997-1037

The rearrangement of spiroepoxycyclohexadienones to benzo[1,3]dioxoles is best carred out in a non polar solvent (toluene, CCl₄) in presence of TBDMSCl. Application to the synthesis of naphthalene and tetrahydronaphthalene derivatives is described.

Full text of DOI:10.1055/s-1997-1037

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