Tetrahedron Letters p. 485 - 486 (1992)
Update date:2022-08-11
Topics:
Paquet
Fellous
Stringat
Fabre
Pure pentanal is irradiated with a frequency tripled Nd-YAG laser in the intensity interval 0.1-1 MW. cm-2. Alpha-dione and α-ketol are formed selectively with quantum yields of 5.5 and 38%, respectively. As only the S1 state of the pentanal is excited, the results obtained are explicable as a dynamic effect in connection with the order of the reactions.
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