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ChemComm
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DOI: 10.1039/C6CC06492B
COMMUNICATION
Journal Name
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(a) X. Yu, S. Zhong, X. Li, Y. Tu, S. Yang, R. M. V. Horn, C. Ni, D.
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In summary, we have successfully synthesized a fullerene C60-
Dawson POM hybrid for the first time and investigated in
detail its aggregation behavior in bulk solutions. Driven by the
unique self-assembly algorithms exhibited by both C60 and
POMs, the C60-POM hybrid can exhibit peculiar aggregation
behavior, which has been demonstrated by the formation of
onionlike structures. The structural persistance of these
aggregates towards the change of solvents reveals the strong
intermolecular interactions, which is in contrast to their fragile
counterparts formed by traditional surfactants. The rich
magnetic, electrochemical and photoresponsive properties of
the onionlike structures imply their potential applications in
material and life sciences. Current work also implies that
traditional amidation can be a facile and clean strategy to
covalently link C60 and POMs, which opens the door for the
upcoming of a thoroughly new family of amphiphiles. We
suppose these initial findings could initiate an enthusiasm on
further explorations of new C60-POM hybrid, which can not
only add more interesting building blocks for supramolecular
chemistry, but also provide new opportunities in other related
fields.
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This work was financially supported by the Hundred Talents
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