Chemical Communications p. 333 - 334 (1996)
Update date:2022-08-18
Topics:
Adams, David R.
Bailey, Patrick D.
Collier, Ian D.
Leah, Stephen A. H.
Ridyard, Colin
The mechanism for the rapid rearrangement of the adamantyl cation (1-yl → 2-yl, or vice versa) in sulfuric acid utilises catalytic adamantane in an intermolecular hydride transfer reaction; a slower rearrangement mechanism involves reversible ring-opening of the adamantyl skeleton, and allows incorporation of high levels of deuterium.
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