Bulletin of the Chemical Society of Japan p. 1257 - 1261 (1992)
Update date:2022-08-17
Topics:
Yamashita, Masakazu
Tashika, Haruyoshi
Uchida, Masaya
Alkyl vinyl ketones and acrylic esters were hydroacylated with organotetracarbonylferrates to the corresponding 1,4-diketones and 4-oxo carboxylic acid derivatives in good yield in dipolar aprotic solvents such as N,N-dimethylacetamide.Addition of 18-crown-6 improved the yield. cis-Jasmone and γ-jasmolactone were synthesized by use of these reactions.
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