Experimental and computational studies on the [3,3]- and [3,5]-sigmatropic rearrangements of acetoxycyclohexadienones: A non-ionic mechanism for acyl migration

DOI: 10.1021/ja4077364

Source and publish data:

Journal of the American Chemical Society p. 14438 - 14447 (2013)

Update date:2022-08-10

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Authors:

Sharma, Shikha

Rajale, Trideep

Cordes, David B.

Hung-Low, Fernando

Birney, David M.

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Article abstract of DOI:10.1021/ja4077364

Flash vacuum pyrolysis studies of substituted 6-acetoxy-2,4- cyclohexadienones (3 and 10) from 300 to 500 C provide strong experimental evidence that direct [3,5]-sigmatropic rearrangements in these molecules are favored over the more familiar [3,3]-sigma

Full text of DOI:10.1021/ja4077364

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