Dalton Transactions
Communication
showed higher catalytic activity than UiO-66-Cr(CO)3 and 13 H. L. Jiang, D. Feng, T. F. Liu, J. R. Li and H. C. Zhou,
UiO-67-Cr(CO)3. It is noteworthy that UiO-67-M(CO)3 exhibited J. Am. Chem. Soc., 2012, 134, 14690.
higher activity than UiO-66-M(CO)3 due to the high accessibil- 14 S. Chavan, J. G. Vitillo, M. J. Uddin, F. Bonino, C. Lamberti,
ity of substrates to catalytically active sites attributable to large
pores of UiO-67. The recovered UiO-67-Mo(CO)3 was found to
E. Groppo, K. P. Lillerud and S. Bordiga, Chem. Mater.,
2010, 22, 4602.
be recycled without significant loss of its catalytic activity, 15 J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou,
suggesting that the catalytically active oxomolybdenum species
are stably present in UiO-67 and act as a reusable hetero-
geneous catalyst.
C. Lamberti, S. Bordiga and K. P. Lillerud, J. Am. Chem.
Soc., 2008, 130, 13850.
16 C. A. Bauer, T. V. Timofeeva, T. B. Settersten,
B. D. Patterson, V. H. Liu, B. A. Simmons and
M. D. Allendorf, J. Am. Chem. Soc., 2007, 129, 7136.
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S. Kitagawa, Adv. Mater., 2011, 23, 3294.
18 S. S. Kaye and J. R. Long, J. Am. Chem. Soc., 2008, 130, 806.
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21 T. Kamegawa, M. Saito, T. Sakai, M. Matsuoka and
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Acknowledgements
The present work was supported by a Grant-in-Aid for Scienti-
fic Research (KAKENHI) from the Ministry of Education,
Culture, Sports, Science and Technology of Japan (No.
21550192).
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