Syntheses and Reaction of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate

Article abstract of DOI:10.1246/bcsj.66.472

Four silane coupling agents, 1H,1H,2H,2H-polyfluoroalkyl(dimethoxy)(methyl)silanes (1H,1H,2H,2H-henicosafluorododecyl(dimethoxy)(methyl)silane, C10F21C2H4Si(CH3)(OCH3)2, 1H,1H,2H,2H-heptadecafluorodecyl(dimethoxy)(methyl)silane, C8F17C2H4Si(CH3)(OCH3)2, 1H,1H,2H,2H-tridecafluorooctyl(dimethoxy)(methyl)silane, C6F13C2H4Si(CH3)(OCH3)2, and 1H,1H,2H,2H-nonafluorohexyl(dimethoxy)(methyl)silane, C4F9C2H4Si(CH3)(OCH3)2), were prepared by the hydrosilylation of dichloro(methyl)silane with the corresponding 1H,1H,2H,2H-polyfluoro-1-alkene in the presence of hydrogen hexachloroplatinate(IV), followed by the reaction with sodium methoxide.The surface modification of glass plate was attempted uisng these products.From measurements of the contact angles θ(deg) of water and oleic acid against a modified glass plate surface, the coupling agents were found to have high modification ability.The oxidation resistance of the modified glass surface was also investigated.