Catalytic organic solid gas reaction: Kinetic and mechanism

Article abstract of DOI:10.1080/10587259408027165

The alkylation of solid 4-tertiobutylphenol by gaseous isobutene in the presence of a catalyst has been studied according to different parameters such as, temperature, initial pressure of isobutene, proportion of catalyst and the granulometry of the catalyst and the solid reactant. Among the predefined kinetic models, the unreacted core model for spherical particles of unchanging size is the best adapted to the experimental results. Based on this model, a mechanism is proposed involving the intervention of a carbocation.

Full text of DOI:10.1080/10587259408027165

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Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
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Catalytic Organic Solid Gas Reaction:
Kinetic and Mechanism
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A. Selatnia , J. Bassus , R. Lamartine & C. Duchamp
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Université Claude Bernard, Laboratoire de Chimie Industrielle , 43
bd du 11 novembre 1918, 69622, VILLEURBANNE, Cedex, FRANCE.
Published online: 24 Sep 2006.
To cite this article: A. Selatnia , J. Bassus , R. Lamartine & C. Duchamp (1994) Catalytic Organic Solid
Gas Reaction: Kinetic and Mechanism, Molecular Crystals and Liquid Crystals Science and Technology.
Section A. Molecular Crystals and Liquid Crystals, 248:1, 71-79, DOI: 10.1080/10587259408027165
To link to this article: http://dx.doi.org/10.1080/10587259408027165
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