Journal of Organic Chemistry p. 6379 - 6387 (2017)
Update date:2022-08-16
Topics:
Alonso, Concepción
González, María
Palacios, Francisco
Rubiales, Gloria
Both experimental and computational studies for the cycloaddition reaction between N-(3-pyridyl)aldimines and acetylenes where 1,5-naphthyridines are obtained are reported. The reaction of benzaldimine with a methoxycarbonyl group in position 2 with phenyl acetylene, styrene, and indene afforded polycyclic isoindolone derivatives. The mechanism of reaction of N-(3-pyridyl)aldimines with olefins can be explained by an asynchronous [4+2] cycloaddition; in the case of acetylenes, the obtained results suggest a stepwise mechanism through a 3-azatriene.
View MoreLiaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Jiaozuo Zhongwen Trading Coporation Limited
Contact:+86 0391-3553810
Address:East Renmin Road
shijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Zhongshan Haihong Medicine Co., Ltd.
Contact:86-0760-86925778 (0)18824993998
Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Hangzhou Share Chemical Co., Ltd
Contact:+86-57187093700
Address:Hang Xing Road
Doi:10.1021/jacs.8b04699
(2018)Doi:10.1021/ja02248a009
(1917)Doi:10.1016/j.cclet.2021.05.016
(2021)Doi:10.1073/pnas.1611096114
(2017)Doi:10.2478/s11696-013-0357-1
(2013)Doi:10.1359/jbmr.2001.16.5.868
(1905)