
Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1920 - 1921 (1992)
Update date:2022-08-17
Topics:
Rudchenko, V. F.
Ignatov, S. M.
Kostyanovskii, R. G.
The chlorination of N-alkoxy-N'-alkylureas (1) by the action of t-BuOCl proceeds regiospecifically to give stable N-chloro-N-alkoxy-N'-alkylureas (2).The alcoholysis of 2 leads to N,N-dialkoxy-N'-alkylureas (3).The alkaline hydrolysis of 3 is a new, convenient method for the preparation of dialkoxyamines.Keywords: N-alkoxy-N'-alkylureas, N-chloro-N-alkoxy-N'-aklylureas, N,N-dialkoxy-N'-alkylureas, dialkoxyamines.
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