Reaction of Hydroxymethyl- and Alkyl-Substituted Azulenes with Manganese Dioxide

DOI: 10.1002/hlca.19950780603

Source and publish data:

Helvetica Chimica Acta p. 1408 - 1418 (1995)

Update date:2022-08-16

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Authors:

Fallahpour, Reza-Ali

Sigrist, Rolf

Hansen, Hans-Juergen

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Article abstract of DOI:10.1002/hlca.19950780603

It is shown that the 2-(hydroxymethyl)-1-methylazulenes 6 are being oxidized by activated MnO2 in CH2Cl2 at room temperature to the corresponding azulene-1,2-dicarbaldehydes 7 (Scheme 2).Extension of the MnO2 oxidation reaction to 1-methyl- and/or 3-methy

Full text of DOI:10.1002/hlca.19950780603

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