On the preparation of 1H-perfluoroalkanes and a mechanism for the reduction of perfluoroalkyl iodides

DOI: 10.1016/0022-1139(94)03176-Z

Source and publish data:

Journal of Fluorine Chemistry p. 61 - 68 (1995)

Update date:2022-08-11

Topics:

Authors:

Howell, J.L.

Muzzi, B.J.

Rider, N.L.

Aly, E.M.

Abouelmagd, M.K.

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Article abstract of DOI:10.1016/0022-1139(94)03176-Z

1H-Perfluoroalkanes are prepared by sodium methoxide reduction of 1-iodoperfluoroalkanes.The experimental evidence indicates that the reaction proceeds either through a radical or a thermal mechanism.We have found that a high yield of 1H-perfluoroalkanes at complete conversion can be accomplished at atmospheric pressure using technology. - Keywords: 1H-Perfluoroalkanes; Methyl hypoiodide; Reduction; Mass spectrometry

Full text of DOI:10.1016/0022-1139(94)03176-Z

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