Chemistry Letters p. 1679 - 1682 (1983)
Update date:2022-08-11
Topics:
Niiyama, Hiroo
Tamai, Shoji
Saito, Yoshinori
Echigoya, Etsuro
Monomethylamine is dehydrogenated to yield hydrogencyanide by the catalysis of 12-tungstophosphates at temperature range of 400-500 deg C.Simultaneous hydrogenolysis to yield methane and ammonia also observed.Typical solid acid catalysts, such as Al2O3 or SiO2-Al2O3 have no activity for the reaction.Catalytic activity for the dehydrogenation might be ascribed to the affinity of polyanion to hydrogen atoms.
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