Bis[bis(methylthio)lithiomethyl]dimethylsilanes: A useful reagent for the synthesis of polysilacarbacycles via disilylation

DOI: 10.1016/S0040-4039(98)00457-2

Source and publish data:

Tetrahedron Letters p. 3193 - 3196 (1998)

Update date:2022-08-11

Topics:

Authors:

Shimizu, Masaki

Iwakubo, Masayuki

Nishihara, Yasushi

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(98)00457-2

Bis[bis(methylthio)lithiomethyl]dimethylsilane was generated from bis[bis(methylthio)methyl]dimethylsilane by deprotonation with t-BuLi in THF and allowed to react with various dichloro(poly)silanes to give the corresponding 4- to 7-membered polysilacarba

Full text of DOI:10.1016/S0040-4039(98)00457-2

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