Russian Chemical Bulletin p. 1280 - 1283 (1998)
Update date:2022-08-29
Topics:
Nho
Butov
Dumskii
Sabirov
Urazbaev
Monakov
The kinetics and mechanism of thermal decomposition of adamantyl-containing organosilicon peroxides in a solution in n-nonane were studied. The relationship between the structure of the peroxide and the rate and mechanism of thermolysis was established. The effect of the peroxide structure on the electronic characteristics of the peroxide bond was studied by the MNDO method. The heterolytic rearrangement occurring during the decomposition of peroxides was analyzed.
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